Preparation and characterization of methacrylate hydrogels for zeta potential control

A technique based on the measurement of streaming potentials has been developed to evaluate the effects of hydrophilic coatings on electroosmotic flow. The apparatus and procedure are described as well as some results concerning the electrokinetic potential of glass capillaries as a function of ionic strength, pH, and temperature. The effect that turbulence and entrance flow conditions have on accurate streaming potential measurements is discussed. Various silane adhesion promoters exhibited only a slight decrease in streaming potential. A coating utilizing a glycidoxy silane base upon which methylcellulose is applied affords a six-fold decrease over uncoated tubes. Hydrophilic methacrylate gels show similar streaming potential behavior, independent of the water content of the gel. By introduction of positive or negative groups into the hydrophilic methacrylate gels, a range of streaming potential values are obtained having absolute positive or negative signs

Memory effects on the statistics of fragmentation

We investigate through extensive molecular dynamics simulations the fragmentation process of two-dimensional Lennard-Jones systems. After thermalization, the fragmentation is initiated by a sudden increment to the radial component of the particles' velocities. We study the effect of temperature of the thermalized system as well as the influence of the impact energy of the ``explosion'' event on the statistics of mass fragments. Our results indicate that the cumulative distribution of fragments follows the scaling ansatz $F(m)\propto m^{-\alpha}\exp{[-(m/m_0)^\gamma]}$, where $m$ is the mass, $m_0$ and $\gamma$ are cutoff parameters, and $\alpha$ is a scaling exponent that is dependent on the temperature. More precisely, we show clear evidence that there is a characteristic scaling exponent $\alpha$ for each macroscopic phase of the thermalized system, i.e., that the non-universal behavior of the fragmentation process is dictated by the state of the system before it breaks down.Comment: 5 pages, 8 figure

Physical regularization for the spin-1/2 Aharonov-Bohm problem in conical space

We examine the bound state and scattering problem of a spin-one-half particle undergone to an Aharonov-Bohm potential in a conical space in the nonrelativistic limit. The crucial problem of the \delta-function singularity coming from the Zeeman spin interaction with the magnetic flux tube is solved through the self-adjoint extension method. Using two different approaches already known in the literature, both based on the self-adjoint extension method, we obtain the self-adjoint extension parameter to the bound state and scattering scenarios in terms of the physics of the problem. It is shown that such a parameter is the same for both situations. The method is general and is suitable for any quantum system with a singular Hamiltonian that has bound and scattering states.Comment: Revtex4, 5 pages, published versio

Efficient formalism for large scale ab initio molecular dynamics based on time-dependent density functional theory

A new "on the fly" method to perform Born-Oppenheimer ab initio molecular dynamics (AIMD) is presented. Inspired by Ehrenfest dynamics in time-dependent density functional theory, the electronic orbitals are evolved by a Schroedinger-like equation, where the orbital time derivative is multiplied by a parameter. This parameter controls the time scale of the fictitious electronic motion and speeds up the calculations with respect to standard Ehrenfest dynamics. In contrast to other methods, wave function orthogonality needs not be imposed as it is automatically preserved, which is of paramount relevance for large scale AIMD simulations.Comment: 5 pages, 3 color figures, revtex4 packag

Sistemas de produção em policultivo de mandioca, milho e caupi para a microrregião Bragantina-Pará.

bitstream/item/33619/1/CPATU-CirTec4.pd

Total Molecular Gas Masses of Planck - Herschel Selected Strongly Lensed Hyper Luminous Infrared Galaxies

We report the detection of CO(1 - 0) line emission from seven Planck and Herschel selected hyper luminous (LIR(8-1000um) > 10^13Lsun) infrared galaxies with the Green Bank Telescope (GBT). CO(1 - 0) measurements are a vital tool to trace the bulk molecular gas mass across all redshifts. Our results place tight constraints on the total gas content of these most apparently luminous high-z star-forming galaxies (apparent IR luminosities of LIR > 10^(13-14) Lsun), while we confirm their predetermined redshifts measured using the Large Millimeter Telescope, LMT (zCO = 1.33 - 3.26). The CO(1 - 0) lines show similar profiles as compared to Jup = 2 -4 transitions previously observed with the LMT. We report enhanced infrared to CO line luminosity ratios of = 110 (pm 22) Lsun(K km s^-1 pc^-2)^-1 compared to normal star-forming galaxies, yet similar to those of well-studied IR-luminous galaxies at high-z. We find average brightness temperature ratios of = 0.93 (2 sources), = 0.34 (5 sources), and = 0.18 (1 source). The r31 and r41 values are roughly half the average values for SMGs. We estimate the total gas mass content as uMH2 = (0.9 - 27.2) x 10^11(alphaCO/0.8)Msun, where u is the magnification factor and alphaCO is the CO line luminosity to molecular hydrogen gas mass conversion factor. The rapid gas depletion times are, on average, tau = 80 Myr, which reveal vigorous starburst activity, and contrast the Gyr depletion timescales observed in local, normal star-forming galaxies.Comment: published in MNRAS, 9pages, 5fig